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Abstract. As the largest active carbon reservoir on Earth, the ocean is a cornerstone of the global carbon cycle, playing a pivotal role in modulating ocean health and regulating climate. Understanding these crucial roles requires access to a broad array of data products documenting the changing chemistry of the global ocean as a vast and interconnected system. This review article provides a comprehensive overview of 60 existing ocean carbonate chemistry data products, encompassing compilations of cruise datasets, derived gap-filled data products, model simulations, and compilations thereof. It is intended to help researchers identify and access data products that best align with their research objectives, thereby advancing our understanding of the ocean's evolving carbonate chemistry. 

Abstract. Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere in a changing climate is critical to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe and synthesize datasets and methodologies to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO2 emissions (EFOS) are based on energy statistics and cement production data, while emissions from land-use change (ELUC) are based on land-use and land-use change data and bookkeeping models. Atmospheric CO2 concentration is measured directly, and its growth rate (GATM) is computed from the annual changes in concentration. The global net uptake of CO2 by the ocean (SOCEAN, called the ocean sink) is estimated with global ocean biogeochemistry models and observation-based fCO2 products (fCO2 is the fugacity of CO2). The global net uptake of CO2 by the land (SLAND, called the land sink) is estimated with dynamic global vegetation models. Additional lines of evidence on land and ocean sinks are provided by atmospheric inversions, atmospheric oxygen measurements, and Earth system models. The sum of all sources and sinks results in the carbon budget imbalance (BIM), a measure of imperfect data and incomplete understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the year 2023, EFOS increased by 1.3 % relative to 2022, with fossil emissions at 10.1 ± 0.5 GtC yr−1 (10.3 ± 0.5 GtC yr−1 when the cement carbonation sink is not included), and ELUC was 1.0 ± 0.7 GtC yr−1, for a total anthropogenic CO2 emission (including the cement carbonation sink) of 11.1 ± 0.9 GtC yr−1 (40.6 ± 3.2 GtCO2 yr−1). Also, for 2023, GATM was 5.9 ± 0.2 GtC yr−1 (2.79 ± 0.1 ppm yr−1; ppm denotes parts per million), SOCEAN was 2.9 ± 0.4 GtC yr−1, and SLAND was 2.3 ± 1.0 GtC yr−1, with a near-zero BIM (−0.02 GtC yr−1). The global atmospheric CO2 concentration averaged over 2023 reached 419.31 ± 0.1 ppm. Preliminary data for 2024 suggest an increase in EFOS relative to 2023 of +0.8 % (−0.2 % to 1.7 %) globally and an atmospheric CO2 concentration increase by 2.87 ppm, reaching 422.45 ppm, 52 % above the pre-industrial level (around 278 ppm in 1750). Overall, the mean of and trend in the components of the global carbon budget are consistently estimated over the period 1959–2023, with a near-zero overall budget imbalance, although discrepancies of up to around 1 GtC yr−1 persist for the representation of annual to semi-decadal variability in CO2 fluxes. Comparison of estimates from multiple approaches and observations shows the following: (1) a persistent large uncertainty in the estimate of land-use change emissions, (2) low agreement between the different methods on the magnitude of the land CO2 flux in the northern extra-tropics, and (3) a discrepancy between the different methods on the mean ocean sink. This living-data update documents changes in methods and datasets applied to this most recent global carbon budget as well as evolving community understanding of the global carbon cycle. The data presented in this work are available at https://doi.org/10.18160/GCP-2024 (Friedlingstein et al., 2024). 

Abstract The dynamics of marine systems at decadal scales are notoriously hard to predict—hence references to this timescale as the “grey zone” for ocean prediction. Nevertheless, decadal-scale prediction is a rapidly developing field with an increasing number of applications to help guide ocean stewardship and sustainable use of marine environments. Such predictions can provide industry and managers with information more suited to support planning and management over strategic timeframes, as compared to seasonal forecasts or long-term (century-scale) predictions. The most significant advances in capability for decadal-scale prediction over recent years have been for ocean physics and biogeochemistry, with some notable advances in ecological prediction skill. In this paper, we argue that the process of “lighting the grey zone” by providing improved predictions at decadal scales should also focus on including human dimensions in prediction systems to better meet the needs and priorities of end users. Our paper reviews information needs for decision-making at decadal scales and assesses current capabilities for meeting these needs. We identify key gaps in current capabilities, including the particular challenge of integrating human elements into decadal prediction systems. We then suggest approaches for overcoming these challenges and gaps, highlighting the important role of co-production of tools and scenarios, to build trust and ensure uptake with end users of decadal prediction systems. We also highlight opportunities for combining narratives and quantitative predictions to better incorporate the human dimension in future efforts to light the grey zone of decadal-scale prediction. 

Surface ocean biogeochemistry and photochemistry regulate ocean–atmosphere fluxes of trace gases critical for Earth's atmospheric chemistry and climate. The oceanic processes governing these fluxes are often sensitive to the changes in ocean pH (or p CO 2 ) accompanying ocean acidification (OA), with potential for future climate feedbacks. Here, we review current understanding (from observational, experimental and model studies) on the impact of OA on marine sources of key climate-active trace gases, including dimethyl sulfide (DMS), nitrous oxide (N 2 O), ammonia and halocarbons. We focus on DMS, for which available information is considerably greater than for other trace gases. We highlight OA-sensitive regions such as polar oceans and upwelling systems, and discuss the combined effect of multiple climate stressors (ocean warming and deoxygenation) on trace gas fluxes. To unravel the biological mechanisms responsible for trace gas production, and to detect adaptation, we propose combining process rate measurements of trace gases with longer term experiments using both model organisms in the laboratory and natural planktonic communities in the field. Future ocean observations of trace gases should be routinely accompanied by measurements of two components of the carbonate system to improve our understanding of how in situ carbonate chemistry influences trace gas production. Together, this will lead to improvements in current process model capabilities and more reliable predictions of future global marine trace gas fluxes. 

Abstract We use a statistical emulation technique to construct synthetic ensembles of global and regional sea‐air carbon dioxide (CO₂) flux from four observation‐based products over 1985–2014. Much like ensembles of Earth system models that are constructed by perturbing their initial conditions, our synthetic ensemble members exhibit different phasing of internal variability and a common externally forced signal. Our synthetic ensembles illustrate an important role for internal variability in the temporal evolution of global and regional CO₂flux and produce a wide range of possible trends over 1990–1999 and 2000–2009. We assume a specific externally forced signal and calculate the rank of the observed trends within the distribution of statistically modeled synthetic trends during these periods. Over the decade 1990–1999, three of four observation‐based products exhibit small negative trends in globally integrated sea‐air CO₂flux (i.e., enhanced ocean CO₂absorption with time) that are within one standard deviation of the mean in their respective synthetic ensembles. Over the decade 2000–2009, however, three products show large negative trends in globally integrated sea‐air CO₂flux that have a low rate of occurrence in their synthetic ensembles. The largest positive trends in global and Southern Ocean flux over 1990–1999 and the largest negative trends over 2000–2009 fall nearly two standard deviations away from the mean in their ensembles. Our approach provides a new perspective on the important role of internal variability in sea‐air CO₂flux trends, and furthers understanding of the role of internal and external processes in driving observed sea‐air CO₂flux variability. 

Abstract. Accurate assessment of anthropogenic carbon dioxide (CO2) emissions andtheir redistribution among the atmosphere, ocean, and terrestrial biospherein a changing climate is critical to better understand the global carboncycle, support the development of climate policies, and project futureclimate change. Here we describe and synthesize data sets and methodologies toquantify the five major components of the global carbon budget and theiruncertainties. Fossil CO2 emissions (EFOS) are based on energystatistics and cement production data, while emissions from land-use change(ELUC), mainly deforestation, are based on land use and land-use changedata and bookkeeping models. Atmospheric CO2 concentration is measureddirectly, and its growth rate (GATM) is computed from the annualchanges in concentration. The ocean CO2 sink (SOCEAN) is estimatedwith global ocean biogeochemistry models and observation-baseddata products. The terrestrial CO2 sink (SLAND) is estimated withdynamic global vegetation models. The resulting carbon budget imbalance(BIM), the difference between the estimated total emissions and theestimated changes in the atmosphere, ocean, and terrestrial biosphere, is ameasure of imperfect data and understanding of the contemporary carboncycle. All uncertainties are reported as ±1σ. For the year 2021, EFOS increased by 5.1 % relative to 2020, withfossil emissions at 10.1 ± 0.5 GtC yr−1 (9.9 ± 0.5 GtC yr−1 when the cement carbonation sink is included), and ELUC was 1.1 ± 0.7 GtC yr−1, for a total anthropogenic CO2 emission(including the cement carbonation sink) of 10.9 ± 0.8 GtC yr−1(40.0 ± 2.9 GtCO2). Also, for 2021, GATM was 5.2 ± 0.2 GtC yr−1 (2.5 ± 0.1 ppm yr−1), SOCEAN was 2.9  ± 0.4 GtC yr−1, and SLAND was 3.5 ± 0.9 GtC yr−1, with aBIM of −0.6 GtC yr−1 (i.e. the total estimated sources were too low orsinks were too high). The global atmospheric CO2 concentration averaged over2021 reached 414.71 ± 0.1 ppm. Preliminary data for 2022 suggest anincrease in EFOS relative to 2021 of +1.0 % (0.1 % to 1.9 %)globally and atmospheric CO2 concentration reaching 417.2 ppm, morethan 50 % above pre-industrial levels (around 278 ppm). Overall, the meanand trend in the components of the global carbon budget are consistentlyestimated over the period 1959–2021, but discrepancies of up to 1 GtC yr−1 persist for the representation of annual to semi-decadalvariability in CO2 fluxes. Comparison of estimates from multipleapproaches and observations shows (1) a persistent large uncertainty in theestimate of land-use change emissions, (2) a low agreement between thedifferent methods on the magnitude of the land CO2 flux in the northernextratropics, and (3) a discrepancy between the different methods on thestrength of the ocean sink over the last decade. This living data updatedocuments changes in the methods and data sets used in this new globalcarbon budget and the progress in understanding of the global carbon cyclecompared with previous publications of this data set. The data presented inthis work are available at https://doi.org/10.18160/GCP-2022 (Friedlingstein et al., 2022b). 

Abstract. Accurate assessment of anthropogenic carbon dioxide (CO2) emissions andtheir redistribution among the atmosphere, ocean, and terrestrial biospherein a changing climate – the “global carbon budget” – is important tobetter understand the global carbon cycle, support the development ofclimate policies, and project future climate change. Here we describe andsynthesize data sets and methodology to quantify the five major componentsof the global carbon budget and their uncertainties. Fossil CO2emissions (EFOS) are based on energy statistics and cement productiondata, while emissions from land-use change (ELUC), mainlydeforestation, are based on land use and land-use change data andbookkeeping models. Atmospheric CO2 concentration is measured directlyand its growth rate (GATM) is computed from the annual changes inconcentration. The ocean CO2 sink (SOCEAN) and terrestrialCO2 sink (SLAND) are estimated with global process modelsconstrained by observations. The resulting carbon budget imbalance(BIM), the difference between the estimated total emissions and theestimated changes in the atmosphere, ocean, and terrestrial biosphere, is ameasure of imperfect data and understanding of the contemporary carboncycle. All uncertainties are reported as ±1σ. For the lastdecade available (2010–2019), EFOS was 9.6 ± 0.5 GtC yr−1 excluding the cement carbonation sink (9.4 ± 0.5 GtC yr−1 when the cement carbonation sink is included), andELUC was 1.6 ± 0.7 GtC yr−1. For the same decade, GATM was 5.1 ± 0.02 GtC yr−1 (2.4 ± 0.01 ppm yr−1), SOCEAN 2.5 ±  0.6 GtC yr−1, and SLAND 3.4 ± 0.9 GtC yr−1, with a budgetimbalance BIM of −0.1 GtC yr−1 indicating a near balance betweenestimated sources and sinks over the last decade. For the year 2019 alone, thegrowth in EFOS was only about 0.1 % with fossil emissions increasingto 9.9 ± 0.5 GtC yr−1 excluding the cement carbonation sink (9.7 ± 0.5 GtC yr−1 when cement carbonation sink is included), and ELUC was 1.8 ± 0.7 GtC yr−1, for total anthropogenic CO2 emissions of 11.5 ± 0.9 GtC yr−1 (42.2 ± 3.3 GtCO2). Also for 2019, GATM was5.4 ± 0.2 GtC yr−1 (2.5 ± 0.1 ppm yr−1), SOCEANwas 2.6 ± 0.6 GtC yr−1, and SLAND was 3.1 ± 1.2 GtC yr−1, with a BIM of 0.3 GtC. The global atmospheric CO2concentration reached 409.85 ± 0.1 ppm averaged over 2019. Preliminarydata for 2020, accounting for the COVID-19-induced changes in emissions,suggest a decrease in EFOS relative to 2019 of about −7 % (medianestimate) based on individual estimates from four studies of −6 %, −7 %,−7 % (−3 % to −11 %), and −13 %. Overall, the mean and trend in thecomponents of the global carbon budget are consistently estimated over theperiod 1959–2019, but discrepancies of up to 1 GtC yr−1 persist for therepresentation of semi-decadal variability in CO2 fluxes. Comparison ofestimates from diverse approaches and observations shows (1) no consensusin the mean and trend in land-use change emissions over the last decade, (2)a persistent low agreement between the different methods on the magnitude ofthe land CO2 flux in the northern extra-tropics, and (3) an apparentdiscrepancy between the different methods for the ocean sink outside thetropics, particularly in the Southern Ocean. This living data updatedocuments changes in the methods and data sets used in this new globalcarbon budget and the progress in understanding of the global carbon cyclecompared with previous publications of this data set (Friedlingstein et al.,2019; Le Quéré et al., 2018b, a, 2016, 2015b, a, 2014,2013). The data presented in this work are available at https://doi.org/10.18160/gcp-2020 (Friedlingstein et al., 2020). 

Abstract This contribution to the RECCAP2 (REgional Carbon Cycle Assessment and Processes) assessment analyzes the processes that determine the global ocean carbon sink, and its trends and variability over the period 1985–2018, using a combination of models and observation‐based products. The mean sea‐air CO₂flux from 1985 to 2018 is −1.6 ± 0.2 PgC yr⁻¹based on an ensemble of reconstructions of the history of sea surface pCO₂(pCO₂products). Models indicate that the dominant component of this flux is the net oceanic uptake of anthropogenic CO₂, which is estimated at −2.1 ± 0.3 PgC yr⁻¹by an ensemble of ocean biogeochemical models, and −2.4 ± 0.1 PgC yr⁻¹by two ocean circulation inverse models. The ocean also degasses about 0.65 ± 0.3 PgC yr⁻¹of terrestrially derived CO₂, but this process is not fully resolved by any of the models used here. From 2001 to 2018, the pCO₂products reconstruct a trend in the ocean carbon sink of −0.61 ± 0.12 PgC yr⁻¹ decade⁻¹, while biogeochemical models and inverse models diagnose an anthropogenic CO₂‐driven trend of −0.34 ± 0.06 and −0.41 ± 0.03 PgC yr⁻¹ decade⁻¹, respectively. This implies a climate‐forced acceleration of the ocean carbon sink in recent decades, but there are still large uncertainties on the magnitude and cause of this trend. The interannual to decadal variability of the global carbon sink is mainly driven by climate variability, with the climate‐driven variability exceeding the CO₂‐forced variability by 2–3 times. These results suggest that anthropogenic CO₂dominates the ocean CO₂sink, while climate‐driven variability is potentially large but highly uncertain and not consistently captured across different methods.